La molécule de pentaborane est constituée de cinq atomes de bore disposés selon un arrangement pyramidal à base carrée. Data from NIST Standard Reference Database 69: The National Institute of Standards and Technology (NIST) Dalton Trans. © 2018 by the U.S. Secretary of Commerce Icosahedron Structure . Copyright for NIST Standard Reference Data is governed by If an internal link led you here, you may wish to change the link to point directly to the intended article. Journal of Molecular Structure 1995, 346, 1-11. 1lambda~5~,2lambda~5~,3lambda~5~,4lambda~5~,5lambda~5~-Tricyclo[2.1.0.0~1,3~]pentaborane, [BH3]1[BH2]2[BH]13[BH2]2[BH3]3 and Informatics. Structure, properties, spectra, suppliers and links for: Pentaborane(11), 18433-84-6. L'ensemble est qualifié de cage nido, d'où la dénomination IUPAC de nido-pentaborane(9). m-3)[8]. Standard Reference Data Act. Technology, Office of Data shall not be liable for any damage that may result from The Journal of Chemical Physics 1954, 22 (6) , 985-988. William N. Lipscomb. Pentaborane can refer to: Pentaborane(9) (B 5 H 9) Pentaborane(11) (B 5 H 11) This set index page lists chemical compounds articles associated with the same name. been selected on the basis of sound scientific judgment. The structure of gaseous 1-(dichloroboryl)pentaborane(9), 1-(Cl 2 B)B 5 H 8, has been determined by electron diffraction. CopyCopied, InChI=1S/B5H11/c1-3-4-2-5(1,3)4/h5H,3-4H2,1-2H3 Content is available under CC BY-SA 3.0 unless otherwise noted. Pentaborane- 9 is the only known exception, having a square pyramidal arrange- ment of boron atoms. DOI: 10.1016/0022-2860(95)91353-X. 3 hexaborane and decaborane among those listed earlier. All rights reserved. The molecular structures of pentaborane(9) with halogen substituents in apical and basal positions, determined by electron diffraction and theoretical calculations. the These include tetraborane, pentaborane -11, .. 2 Figure 1. Professor emeritus Kenneth W. Hedberg. [H][B]123[B]456([H])[H][B]141([H])[H][B]211([H])[H][B]351([H])[H]6, Droit d'auteur : les textes des articles sont disponibles sous, V. R. Miller, G. E. Ryschkewitsch, D. F. Gaines et N. Keipe, Programme International sur la Sécurité des Substances Chimiques, National Institute for Occupational Safety and Health. errors or omissions in the Database. However, NIST makes no warranties to that effect, and NIST Database and to verify that the data contained therein have Its structure, including hydrogens is given in Figure 2. uses its best efforts to deliver a high quality copy of the DOI: 10.1039/B402688H. Dalton Trans. CopyCopied, Validated by Experts, Validated by Users, Non-Validated, Removed by Users, Predicted data is generated using the ACD/Labs Percepta Platform - PhysChem Module, Click to predict properties on the Chemicalize site, For medical information relating to Covid-19, please consult the, ACD/Labs Percepta Platform - PhysChem Module, Compounds with the same molecular formula, Search Google for structures with same skeleton. Chaque atome de bore est lié à un ligand hydrure terminal, tandis que quatre ligands hydrure pontants sont liés aux atomes de bore de la base. DOI: 10.1063/1.1740319. on behalf of the United States of America. InChI=1S/B5H11/c6-1-3-2-5(3,7-2)4(1,3,6)8-5/h4-5H,1-3H2, National Institute of Standards and DOI: 10.1039/B402688H. 2004, 58 (11) , 1719-1725. The molecular structures of pentaborane(9) with halogen substituents in apical and basal positions, determined by electron diffraction and theoretical calculations. La toxicité aiguë du pentaborane le rend immédiatement dangereux pour la santé et pour la vie au-delà de 1 ppm[9]. Structure, synthèse et propriétés. 2004, 58 (11) , 1719-1725. The results confirm that the molecule consists of a pentaborane(9) cage substituted at the apical boron atom, B(1), by a dichloroboryl group; the BCl 2 moiety is essentially free to rotate about the exo B–B bond. CopyCopied, CSID:34987102, http://www.chemspider.com/Chemical-Structure.34987102.html (accessed 03:22, Nov 27, 2020) Stable pentaborane, B5H9, is one of the boron hydrides, a short, comparatively little studied series of extraordinary compounds for which a satisfactory elementary valence theory is lacking. CopyCopied, OPSKXWPMAKCNOG-UHFFFAOYSA-N Last edited on 17 October 2018, at 00:19. IUPAC Standard InChIKey: LVRADNQEQFFNNW-UHFFFAOYSA-N CAS Registry Number: 18433-84-6 Chemical structure: This structure is also available as a 2d Mol file; Other names: Boron hydride (B5H11) Information on this page: Notes 18433-84-6 - SYZYDYTXOCWOBF-UHFFFAOYSA-N - Pentaborane(11) - Similar structures search, synonyms, formulas, resource links, and other chemical information. Structures of the Boron Hydrides. Kolbjørn Hagen.